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To derive ages from such measurements, unprovable assumptions have to be made such as: There is plenty of evidence that the radioisotope dating systems are not the infallible techniques many think, and that they are not measuring millions of years. For example, deeper rocks often tend to give older “ages.” Creationists agree that the deeper rocks are generally older, but not by millions of years.Geologist John Woodmorappe, in his devastating critique of radioactive dating, points out that there are other large-scale trends in the rocks that have nothing to do with radioactive decay.We will deal with carbon dating first and then with the other dating methods.Carbon has unique properties that are essential for life on Earth.Unless this effect (which is additional to the magnetic field issue just discussed) were corrected for, carbon dating of fossils formed in the flood would give ages much older than the true ages.
The common application of such posterior reasoning shows that radiometric dating has serious problems.Also, the Genesis flood would have greatly upset the carbon balance.The flood buried a huge amount of carbon, which became coal, oil, etc., lowering the total C ratio in plants/animals/the atmosphere before the flood had to be lower than what it is now.This also has to be corrected for. Second, the ratio of C in the atmosphere at that time to be estimated, and so partial calibration of the “clock” is possible.Accordingly, carbon dating carefully applied to items from historical times can be useful.
Since the flood was accompanied by much volcanism (see Noah's Flood…, How did animals get from the Ark to isolated places? ), fossils formed in the early post-flood period would give radiocarbon ages older than they really are.